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Effect of pre-intercalation on Li-ion diffusion mapped by topochemical single-crystal transformation and operando investigation

Nature Materials, Published online: 21 March 2024; doi:10.1038/s41563-024-01842-y

Pre-intercalation with alkali-metal ions is attractive for accessing higher reversible capacity and improved rate performance in Li-ion batteries. Topochemical single-crystal transformations in a tunnel-structured positive electrode are used to clarify the effect of pre-intercalation in modifying the host lattice and altering diffusion pathways.Nature Materials, Published online: 21 March 2024; doi:10.1038/s41563-024-01842-yPre-intercalation with alkali-metal ions is attractive for accessing higher reversible capacity and improved rate performance in Li-ion batteries. Topochemical single-crystal transformations in a tunnel-structured positive electrode are used to clarify the effect of pre-intercalation in modifying the host lattice and altering diffusion pathways. Read More 

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